李志勇
個人簡介：
李志勇，河南師范大學平原學者，博士生導師。主要從事離子液體與低碳能源相關(guān)研究，任中國化工學會化工大數(shù)據(jù)與智能設(shè)計專業(yè)委員會委員，中國化學會化學熱力學與熱分析專業(yè)委員會第一屆青年委員會副主任，入選河南省高層次人才（C類），河南省高?？萍紕?chuàng)新人才支持計劃，河南省高校青年骨干教師培養(yǎng)計劃，河南省教育廳學術(shù)技術(shù)帶頭人，被聘為Green Energy Environ. 和鹽湖研究兩個期刊的青年編委。先后在Angew. Chem., Green Chem., TRAC Trends Anal. Chem., Phys. Chem. Chem. Phys.等國際重要期刊發(fā)表SCI論文100余篇，論文被SCI他引4000余次，獲河南省自然科學獎一等獎1項，入選全球前2%頂尖科學家榜單(World’s Top 2% Scientists 2022, 2023，斯坦福大學)。
E-mail:lizhiyong03@126.com; yli@htu.edu.cn
ORCiD:0000-0002-1865-864X Scopus Author ID: 57022563800
歡迎有志從事離子液體、綠色化學、低碳能源等領(lǐng)域研究的同學加盟！長期招聘博士后加盟合作。
教育經(jīng)歷：
2003.09-2007.06 河南師范大學化學與環(huán)境科學學院 化學 理學學士
2007.09-2010.06 河南師范大學化學與環(huán)境科學學院 物理化學 理學碩士
2013.09-2019.06 河南師范大學化學化工學院 物理化學 理學博士
工作經(jīng)歷：
2010.07 至今 河南師范大學化學化工學院講師、副教授
2019.10 遴選為碩士生導師
2022.12 遴選為博士生導師
主講課程：
《物理化學》、《物理化學實驗》、《化學信息學》、《現(xiàn)代化學進展》、《科技文獻檢索與論文寫作》
研究領(lǐng)域與興趣：
1.功能化離子液體，重點關(guān)注生物相容性離子液體、光響應(yīng)離子液體等領(lǐng)域
2.刺激響應(yīng)乳液，包括乳狀液、微乳液、Pickering乳液
3.氣體捕集與分離，面向碳中和，開展二氧化碳、氨氣等氣體捕集與分離
近年來主持的主要科研項目:
1.國家自然科學基金：紫外/可見光對離子液體乳狀液結(jié)構(gòu)和相行為的調(diào)控，項目編號：21803017, 2019.1-2021.12, 26萬元
2.國家自然科學基金：螺吡喃型離子液體微乳液的結(jié)構(gòu)和相行為的可逆光調(diào)控,項目編號：22273016, 2023.1-2026.12, 54萬元
3.河南省高?？萍紕?chuàng)新團隊：基于離子液體的綠色分離，項目編號：25IRTSTHN002，2025.1-2027.12, 50萬元
4.河南省高?？萍紕?chuàng)新人才，光響應(yīng)離子液體雙水相，項目編號：21HASTIT003, 2021.1-2023.12, 30萬元
代表性論文：
35. Shuaiqi Gao, Yingying Yang, Liyong Zhai, Yang Zhao,* Zhiyong Li, * Huiyong Wang, Jianji Wang*, Alkoxy-functionalized covalent organic Framework membranes for efficient molecular sieving with high water permeance, Sep. Purif. Technol., 2025, 356, 129903.
34. Zhiyong Li, Zhenzhen Wang, Doudou Cao, Yunlei Shi, Yuling Zhao, Huiyong Wang,* Jianji Wang*，Designing bimetallic ionic liquid hybridized molecular sieve adsorbents for efficient ammonia adsorption at high temperature and low content, Sep. Purif. Technol., 2025, 354, 128861.
33. Ruipeng Li, Jingnuo Shi, Xing Zhou, Zhiyong Li*, Yanfei Zhao, Zhimin Liu, and Jianji Wang*, Green Synthesis of Nitriles from Biomass-Derived Aldehydes by Evoking Intrinsic Cooperative Effects of Ionic Liquids, ACS Sustain. Chem. Eng., 2024, 12, 11338–11346.
32. Panpan Zhou, Zhiyong Li*, Zhenzhen Wang, Huiyong Wang, Yang Zhao, Jianji Wang*, Sunlight assisted highly efficient desorption of ammonia by redox graphene hybrid metal–organic framework photothermal conversion adsorbents, Sep. Purif. Technol., 2024, 336, 126348
31. Xiaoyan Pei, Wangyue Song, Yang Zhao and Zhiyong Li*, CO2-switchable amidine-modified ZIF-90- stabilized Pickering emulsions for controllable Knoevenagel condensation reactions, Mol. Syst. Des. Eng., 2024, 9, 278-285.
30. Xiaoyan Pei*, Wangyue Song, Yunlei Shi, Yang Zhao, Zhiyong Li*, CO2-triggered (3-aminopropyl)triethoxysilane-functionalized M-MOF-74 stabilized Pickering emulsions, J. Mol. Liq., 2024, 405, 125022.
29. Liufang Zhao, Xiaoqing Yuan, Huiyong Wang, Yuanchao Pei, Yunlei Shi, Yuling Zhao, Yang Zhao*, Zhiyong Li*, Light-switchable emulsions: From reversible emulsificationdemulsification to controllable microreactors, J. Mol. Liq., 2023, 372, 121166.
28. Xiaoyan Pei*, Wangyue Song, Yunlei Shi, Chao Xu, Zhe Wang, Xiantao Ma, Dong-Li Xu, and Zhiyong Li*, CO2-Switchable Emulsification and Demulsification of Pickering Emulsion Stabilized by Zirconium-Based Metal–Organic Frameworks, ACS Sustain. Chem. Eng., 2023 11, 796-803.
27. Zhiyong Li, Kairui Shi, Liyong Zhai, Zhenzhen Wang, Huiyong Wang, Yang Zhao*, Jianji Wang*, Constructing multiple sites of metal-organic frameworks for efficient adsorption and selective separation of CO2, Sep. Purif. Technol., 2023, 307, 122725.
26. Yilong Li, Zhiyong Li*, Ruipeng Li, Huiyong Wang, Yang Zhao, Yuanchao Pei, Jianji Wang*, Highly efficient triiodide ion adsorption from water by ionic liquid hybrid metal–organic frameworks, J. Mol. Liq., 2023, 370, 121009.
25. Zhiyong Li, Yu Chen, Zhenzhen Wang, Yang Zhao, Qingchun Xia, Jikuan Qiu, Huiyong Wang*, Jianji Wang*, Ionic liquid hybrid metal–organic frameworks for efficient adsorption and selective separation of ammonia at high temperature, Chem. Eng. J., 2023, 464, 142728.
24. Chaojie Pang, Jiage Liu, Rui Peng, Yingying Guo, Zhiyong Li*, Huiyong Wang*, Liquid-phase exfoliation of titanium disulfide nanosheets in aqueous ionic liquid solutions for highly efficient CO2 electroreduction, J. Mol. Liq., 2023, 381, 121814.
23. Xiaoyan Pei*, Wangyue Song, Dong-Li Xu, Qiuju Zhou, Yang Zhao, and Zhiyong Li*, CO2-induced phase transfer of amino-modified ZIF-90 between immiscible liquid phases for recyclable efficient synergistic catalysis, ACS Appl. Nano Mater., 2023, 6, 13, 11291-11298.
22. Ruipeng Li, Xing Zhou, Zhiyong Li*, Yuepeng Wang, Yanfei Zhao, Zhimin Liu*, Changling Yan, Cailing Wu, Yang Zhao, and Jianji Wang*, Intramolecular dehydration of cyclic alcohols to cyclic alkenes via cation- and anion-confined catalysis over ionic liquids, ACS Sustain. Chem. Eng., 2023, 11, 29, 10659-10666.
21. Xiaoyan Pei*, Wangyue Song, Zongwen Zhang, Yang Zhao, and Zhiyong Li*, CO2-Responsive CuI-Ionic Liquid/Zeolitic Imidazolate Frameworks Stabilized Pickering Emulsions for Azide–Alkyne Click Reaction, ACS Appl. Nano Mater., 2023, 6(21), 19972-19980.
20. Xiaoyan Pei, Zhiyong Li*, Huiyong Wang, Qiuju Zhou, Zuodong Liu, and Jianji Wang* CO2-Switchable Phase Separation of Nonaqueous Surfactant-Free Ionic Liquid-Based Microemulsions, ACS Sus. Chem. Eng., 2022, 10, 1777-1785.
19. Zhenzhen Wang, Zhiyong Li*, Huiyong Wang, Yang Zhao, Qingchun Xia, Jikuan Qiu, and Jianji Wang*, Regulating the Pore Microenvironment of Microporous Metal–Organic Frameworks for Efficient Adsorption of Low-Concentration Ammonia, ACS Sus. Chem. Eng., 2022, 10(33), 10945-10954. (most popular article)
18. Xiaoyan Pei*, Chunyu Tian, Yanning Wang, Zhenzhen Li, Zhiyan Xiong, Huiyong Wang, Xiantao Ma, Xinhua Cao and Zhiyong Li*, CO2-Driven reversible transfer of amine-functionalized ZIF-90 between organic and aqueous phases, Chem. Commun., 2022, 58, 10372-10375.
17. Zhenzhen Wang, Zhiyong Li*, Xia-Guang Zhang, Qingchun Xia, Huiyong Wang, Chenlu Wang, Yanlei Wang, Hongyan He, Yang Zhao, and Jianji Wang* Tailoring Multiple Sites of Metal–Organic Frameworks for Highly Efficient and Reversible Ammonia Adsorption, ACS Appl. Mater. Interfaces, 2021, 13, 56025-56034.
16. Xiaoyan Pei*, Jiang Liu, Weihao Rao, Xiantao Ma, and Zhiyong Li*, CO2-Switchable Reversible Phase Transfer of Carbon Dots, Ind. Eng. Chem. Res., 2021, 60(25), 9296-9303.
15. Doudou Cao, Zhiyong Li*, Zhenzhen Wang, Huiyong Wang, Shuaiqi Gao, Yu Wang, Yunlei Shi, Jikuan Qiu, Yang Zhao, Jianji Wang,* Highly Dispersed Ionic Liquids in Mesoporous Molecular Sieves Enable a Record NH3 Absorption, ACS Sus. Chem. Eng., 2021, 9, 16363-16372.
14. Zhiyong Li, Yunlei Shi, Anlian Zhu, Yuling Zhao, Huiyong Wang, Bernard P. Binks* and Jianji Wang*, Light-responsive, reversible emulsification and demulsification of oil-in-water Pickering emulsions for catalysis. Angew. Chem. Int. Ed., 2021, 60, 3928-3933.
13. Huiyong Wang, Jingjing Cui, Yuling Zhao, Zhiyong Li*, Jianji Wang*, Highly efficient separation of 5-hydroxymethylfurfural from imidazolium-based ionic liquids, Green Chem., 2021, 23, 405-411.
12. Zhiyong Li, Anqi Li, Yifan Zhou, Lujun Zhang, Yang Zhao,* Xiaopeng Xuan,* From hydrophobity to hydrophilicity: Design, synthesis, structural transformation and distinguishment of highly symmetric 1,3-bis(carboxymethyl)imidazolium bis(trifluoromethyl)sulfonyl)amide ionic liquids, J. Mol. Struc., 2021, 1231, 129688.
11. Zhiyong Li, Ying Feng, Xiaomin Liu, Huiyong Wang,* Yuanchao Pei, H. Q. Nimal Gunaratne and Jianji Wang*, Light-triggered switchable ionic liquid aqueous two-phase systems, ACS Sus. Chem. Eng., 2020, 8, 15327-15335.
10. Zhiyong Li, Ruipeng Li, Xiaoqing Yuan, Yuanchao Pei, Yuling Zhao, Huiyong Wang, Jianji Wang*, Anionic structural effect in liquid-liquid separation of phenol from model oil by choline carboxylate ionic liquids. Green Energy Environ., 2019, 4, 131-138.
9. Zhiyong Li, Ying Feng, Xiaoqing Yuan, Huiyong Wang, Yuling Zhao, Jianji Wang*, Photo-triggered reversible phase transfer of azobenzene-based ionic liquid surfactants between oil and water. Int. J. Mol. Sci., 2019, 20, 1685.
8. Xiaoqing Yuan, Zhiyong Li*,Ying Feng, Yuanchao Pei, Huiyong Wang, Diandian, Liu, Dayu Wang, Jianji Wang*. Phase behavior and microstructure of azobenzene ionic liquids based photo-responsive microemulsions. J. Mol. Liq., 2019, 227, 805-811.
7. Zhiyong Li, Ying Feng, Xiaoqing Yuan, Yuling Zhao, Jianji Wang*, Structure and performance modulation of photo-responsive ionic liquids. Prog. Chem.(化學進展), 2019, 31, 1550-1559.
6. Zhiyong Li, Xiaoqing Yuan, Ying Feng, Yongkui Chen, Yuling Zhao, Huiyong Wang, Qingli Xu, Jianji Wang*, A reversible conductivity modulation of azobenzene-based ionic liquids in aqueous solutions by UV/Vis light, Phys. Chem. Chem. Phys., 2018, 20, 12808-12816.
5. Zhiyong Li, Huiyong Wang, Mengen Chu, Pengxin Guan, Yang Zhao, Yuling Zhao, Jianji Wang*, Photo-isomerization and light-modulated aggregation behavior of azobenzene-based ionic liquids in aqueous solutions, RSC Adv., 2017, 7, 44688-44695.
4. Zhiyong Li, Yuanchao Pei, Huiyong Wang, Yuling Zhao, Jianji Wang*, Progress in environmentally friendly ionic liquids aqueous two-phase systems. Chin. Sci. Bull.（科學通報）, 2015, 60: 1-9
3. Zhiyong Li, Xinxin Liu, Yuanchao Pei, Jianji Wang*, Mingyuan He. Design of environmentally friendly ionic liquids aqueous two-phase systems for the efficient and high activity extraction of proteins. Green Chem., 2012, 14, 2941-2950.
2. Zhiyong Li, Yuanchao Pei, Huiyong Wang, Jing Fan, Jianji Wang*.Ionic liquids based aqueous two-phase systems and their applications in green separation process. TRAC Trends Anal. Chem., 2010, 29, 1336-1346.
1. Zhiyong Li, Yuanchao Pei, Li Liu, Jianji Wang*. (Liquid+liquid) equilibria for (acetate-based ionic liquids + inorganic salts) aqueous two-phase systems. J. Chem. Thermodyn., 2010, 42, 932-937.
獲得榮譽與獎勵：
1. 《離子液體雙水相對某些生物分子的萃取分離性能研究》河南省優(yōu)秀碩士學位論文，2010年
2. 《Ionic liquids based aqueous two-phase systems and their applications in green separation process》河南省首屆自然科學優(yōu)秀學術(shù)論文一等獎，2011年
3. 《(Liquid+liquid) equilibria for (acetate-based ionic liquids + inorganic salts) aqueous two-phase systems》河南省首屆自然科學優(yōu)秀學術(shù)論文二等獎，2011年
4.離子液體與綠色過程青年新秀，中國化工學會離子液體專業(yè)委員會，2017年
5.離子液體的介觀結(jié)構(gòu)、性行為及性能調(diào)控，河南省教育廳科技成果一等獎，2021年，第三完成人
6.離子液體的介觀結(jié)構(gòu)、性行為及性能調(diào)控，河南省自然科學獎一等獎，2021年，第三完成人
7. ISPT 2024 青年科學家獎，2024年
