張絜

博士，研究員，博士生導(dǎo)師，河南師范大學(xué)特聘教授

Email:   jie.zhang@htu.edu.cn

教育經(jīng)歷:

博士, 中國科學(xué)院蘭州化學(xué)物理研究所，1999

碩士, 中國科學(xué)院青海鹽湖研究所，1996

科研經(jīng)歷：

2013/09—          河南師范大學(xué)，化學(xué)化工學(xué)院，研究員，特聘教授

2010/11—2013/08，美國俄亥俄國家生化試劑公司，研究員，研發(fā)部主任

2004/04—2010/10，美國布魯克黑文國家實驗室，辛辛那提大學(xué)，研究員

2001/06—2004/03，英國諾丁漢大學(xué)，化學(xué)系，研究員

1999/08—2001/06，中國科學(xué)院化學(xué)研究所，博士后

主講課程：

高等無機化學(xué), 無機化學(xué)前沿

研究領(lǐng)域與興趣：

金屬有機合成化學(xué)，硼化學(xué)，均相催化反應(yīng)機理

近年來主持的主要科研項目：

國家自然科學(xué)基金資助項目(2016.01-2019.12)：“新型硼氮空間受阻路易斯酸堿對的合成及其在催化還原二氧化碳中的應(yīng)用”, 批準(zhǔn)號：21571052.

河南省重點科技攻關(guān)項目(2015.01-2016.12)：“新型硼氮空間受阻路易斯酸堿對的合成與催化性能研究”, 批準(zhǔn)號：152102210085.

近期代表性論文：

1.  Jiarui Chang, Fei Fang, Jie Zhang*, Xuenian Chen*,  “Hydrosilylation of Aldehydes and Ketones Catalysed by Bis(phosphinite) Pincer Platinum Hydride Complexes”, Adv. Synth. Catal. 2020, 362, 2709–2715.

2.  Yan-Na Ma, Yan Gao, Yi Jing, Jiaxin Kang, Jie Zhang*, Xuenian Chen*, “Syntheses of Bromo?N?heterocycles through DibromohydantoinPromoted Tandem C?H Amination/Bromination”, J. Org. Chem. 2020, 85, 2918–2926.

3.  Bula Cao, Yazhou Ding, Fei Fang, Jiarui Chang, Jie Zhang*, Shujun Li, Xuenian Chen*, “The stability of group 10 metal POCOP pincer complexes: decomposition/reconstruction pathways of the pincer backbone”, Dalton Trans. 2019, 48, 13760–13768.

4.  Yazhou Ding, Qiang-Qiang Ma, Jiaxin Kang, Jie Zhang*, Shujun Li, Xuenian Chen*, Palladium(II) complexes supported by PBP and POCOP pincer ligands: a comparison of their structure, properties and catalytic activity, Dalton Trans. 2019, 48, 17633–17643.

5.  Xi-Meng Chen, Jin Wang, Si-Cong Liu, Jie Zhang*, Donghui Wei*, Xuenian Chen*, “Controllable syntheses of B/N anionic aminoborane chain complexes by the reaction of NH₃BH₃ with NaH and the mechanistic study”, Dalton Trans. 2019, 48, 14984–14988.

6.  Yan-Na Ma, Yajing Bian, Xin Liu, Jie Zhang*, Xuenian Chen*, “One-Pot Synthesis of Iodo-Dibenzothiazines from 2?Biaryl Sul?des”, J. Org. Chem. 2019, 84, 450?457. 

7.  Shujun Li, Yue Zhao, Huihui Qi, Yanfang Zhou, Shuxia Liu, Xiaoming Ma, Jie Zhang*, Xuenian Chen*, “Boronic acid derivatized lanthanide–polyoxometalates with novel B–OH–Ln and B–O–Nb bridges”,  Chem. Commun. 2019, 55, 2525?2528.

8.      Jie Zhang*, Ting Liu, Qiang-Qiang Ma, Shujun Li, Xuenian Chen*, “A reaction of [2,6-(^tBu₂PO)₂C₆H₃]NiSCH₂Ph with BH₃·THF: borane mediated C–S bond cleavage”, Dalton Trans. 2018, 47, 6018–6024.

9.      Jie Zhang*, Ting Liu, Changgeng Wei, Jiarui Chang, Qiang-Qiang Ma, Shujun Li, Nana Ma*, Xuenian Chen*, “The Reactivity of Mercapto Groups against Boron Hydrides in Pincer Ligated Nickel Mercapto Complexes”, Chem. Asian J. 2018, 13, 3231–3238.

10.  Yan-Na Ma, Chen-Yang Guo, Qianyi Zhao, Jie Zhang*, Xuenian Chen*, “Synthesis of dibenzothiazines from sul?des by one-pot N,O-transfer and intramolecular C–H amination”,  Green Chem. 2018, 20, 2953–2958.

11.  Xi-Meng Chen, Nana Ma, Qian-Fan Zhang, Jin Wang, Xiaoge Feng, Changgeng Wei, Lai-Sheng Wang*, Jie Zhang*, Xuenian Chen*, “Elucidation of the Formation Mechanisms of the Octahydrotriborate Anion (B₃H₈^?) through the Nucleophilicity of the B?H Bond” J. Am. Chem. Soc. 2018, 140, 6718?6726.

12.  Ting Liu, Wenjuan Meng, Qiang-Qiang Ma, Jie Zhang*, Huizhen Li, Shujun Li, Qianyi Zhao, Xuenian Chen*, “Hydroboration of CO₂ Catalyzed by Bis(phosphinite) Pincer Ligated Nickel Thiolate Complexes”, Dalton Trans. 2017, 46, 4504?4509.

13.  Qiang-Qiang Ma, Ting Liu, Anubendu Adhikary, Jie Zhang*, Jeanette A. Krause, Hairong Guan*, “Using CS₂ to Probe the Mechanistic Details of Decarboxylation of Bis(phosphinite)-Ligated Nickel Pincer Formate Complexes”, Organometallics 2016, 35, 4077?4082.

14.  Qiang-Qiang Ma, Ting Liu, Shujun Li, Jie Zhang*, Xuenian Chen*, Hairong Guan*, “Highly Efficient Reduction of Carbon Dioxide with a Borane Catalyzed by Bis(phosphinite) Pincer Ligated Palladium Thiolate Complexes”, Chem. Commun. 2016, 52, 14262?14265.

15.  Hou-Ji Cao, Qianyi Zhao, Qian-Fan Zhang, Jiaxuan Li, Ewan J. M. Hamilton, Jie Zhang*, Lai-Sheng Wang*, Xuenian Chen*, “Catalyst Design Based on Agostic Interactions: Synthesis, Characterization, and Catalytic Activity of Bis(pyrazolyl)borate Copper Complexes”, Dalton Trans. 2016, 45, 10194?10199.

16.  Huizhen Li, Nana Ma, Wenjuan Meng, Judith Gallucci, Yongqing Qiu, Shujun Li, Qianyi Zhao, Jie Zhang*, Ji-Cheng Zhao*, Xuenian Chen*, “Formation Mechanisms, Structure, Solution Behavior and Reactivity of Aminodiborane”, J. Am. Chem. Soc. 2015, 137, 12406?12414.