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          趙茜怡個(gè)人簡(jiǎn)介

          時(shí)間:2015-09-09瀏覽:13558設(shè)置

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             趙茜怡

           

             博士,副教授,碩士生導(dǎo)師

              E-mail: qyzhao@htu.edu.cn

              課題組主頁(yè)鏈接:

              http://www.boronchemistry.net

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          教育與經(jīng)歷:

          2003.09?2007.06 河南師范大學(xué)化學(xué)化工學(xué)院 學(xué)士

          2007.09?2012.06 廈門大學(xué)化學(xué)化工學(xué)院 博士

            

          工作經(jīng)歷:  

          2012.07-至今  河南師范大學(xué)化學(xué)化工學(xué)院講師、副教授

            

          研究領(lǐng)域與興趣:

          1、含硼過(guò)渡金屬配合物的設(shè)計(jì)合成、結(jié)構(gòu)、反應(yīng)性及催化性能研究

          2、新型硼烷衍生物的合成及應(yīng)用研究

              

          近年來(lái)主持的科研項(xiàng)目:

          1、國(guó)家自然科學(xué)基金:鋨硼氮配合物的合成及其在氨/胺硼烷催化脫氫反應(yīng)中的作用機(jī)理研究,項(xiàng)目編號(hào):21501048,2016.1-2018.12。

          2、河南省教育廳科學(xué)技術(shù)研究重點(diǎn)項(xiàng)目:“氨硼烷衍生物的合成與儲(chǔ)氫性能研究,項(xiàng)目編號(hào):14B15003214B150032,2016.1-2018.12。

          3、河南省科技廳科技攻關(guān)項(xiàng)目:鋨基硼氮?dú)鋬?chǔ)氫材料脫氫催化劑的研發(fā),項(xiàng)目編號(hào):182102210377,2018.1-2019.12。

          4、河南省高等學(xué)校重點(diǎn)科研項(xiàng)目:含有抓氫鍵硼基配體配合物的合成及其催化應(yīng)用研究,項(xiàng)目編號(hào):20A1500042020.1-2021.12。  

            

          代表性論文:

          1Qianyi Zhao, Rian D. Dewhurst, Holger Braunschweig, Xuenian Chen. A New Perspective on Borane Chemistry: the Nucleophilicity of the B-H Bonding Pair Electrons. Angew. Chem. Int. Ed. 2019, 58, 3268-3278. (SCI一區(qū)Top, ESI)

          2、Qianyi Zhao, Xin-Ting Guan, Ting Dou, Hou-Ji Cao, Na-Na Ma, Ting Xu, Peng-Hui Gao, Xiao-Hua Kong, Jie Zhang, Xuenian Chen. Synthesis and Characterization of Bis(pyrazolyl) Borate Ni(II) Complexes: Ligand Rearrangement and Transformation. Dalton Trans., 2019, 48, 13242–13247. (SCI二區(qū), ESI)

          3、Qianyi Zhao, Ting Dou, Xin-Ting Guan, Ting Xu, Ming-Jing Chen, Jie Zhang, Xuenian Chen. B–N Cleavage in (9-BBN)bis(pyrazolyl)borate NiII Complexes. Eur. J. Inorg. Chem. 2019, 37243730.(SCI, ESI)

          4Qianyi Zhao, Jiaxuan Li, Na-Na Ma, Chang-Geng Wei, Ting Xu, Bao Li, Jie Zhang, Xuenian Chen. Reactions of AmineBoranes with Oxalic Acid: Substitution on the N or B Atom Leads to Different Spiroborate Compounds. Eur. J. Inorg. Chem. 2018, 26592665.(SCI, ESI)

          5、Qianyi Zhao,Yuan Liang, Ting Xu, Ting Dou, Jie Zhang, Xuenian Chen. Chin. J. Org. Chem. 2018, 38, 32863295. (SCI)

          6Qianyi Zhao, Jiaxuan Li, Ewan J.M. Hamilton, Xuenian Chen. The Continuing Story of the Diammoniate of Diborane. J. Organomet. Chem. 2015, 798, 2429. (SCI, ESI)

          7、Xiao-Yu Cao, Qianyi Zhao, Zhiqun Lin *, Haiping Xia *.The Chemistry of Aromatic Osmacycles. Acc. Chem. Res. 2014, 47(2), 341354. (SCI一區(qū)Top, ESI)

          8、Qianyi Zhao, Xiao-Yu Cao,* Ting Bin Wen, Haiping Xia.* From Osmium Hydrido Vinylidene to Osmacycles: The Key Role of Osmabutadiene Intermediates. Chem.Asian. J. 2013,8, 269275. (SCI二區(qū), ESI)

          9、Qianyi Zhao, Jun Zhu, Zi-Ao Huang, Xiao-Yu Cao,* Haiping Xia.* Conversions of Osmabenzyne and Isoosmabenzene. Chem.Eur. J. 2012,18, 1159711603. (Inside Cover,SCI二區(qū), ESI)

          10Qianyi Zhao, Lei Gong, Chunfa Xu, Jun Zhu,* Xumin He, Haiping Xia.* Stable Iso-osmabenzenes from a Formal [3+3] Cycloaddition Reaction of Metal Vinylidene with Alkynols. Angew. Chem. Int. Ed. 2011, 50, 13541358. (SCI一區(qū)Top, ESI)

            

          授權(quán)專利:

          1、趙茜怡,梁媛,竇婷,張絜,陳學(xué)年.具有催化氨硼烷脫氫活性的鋨雙齒N基配合物及其制備方法, 2020.4.27, CN201810502146.4

          2、趙茜怡,梁媛,竇婷,張絜,陳學(xué)年.具有催化氨硼烷脫氫活性的鋨雙齒二胺配合物及其制備方法, 2020.4.27, CN201810502638.3

          3、趙茜怡,李佳璇,李書軍,張絜,陳學(xué)年.一種雙草酸硼銨鹽[NHR1R2R3][BC4O8]及其制備方法, 2019.10.29, CN201711370835.6

            

          榮譽(yù)與獎(jiǎng)勵(lì):

          2019年,全省教育系統(tǒng)教學(xué)技能競(jìng)賽三等獎(jiǎng)

          2018年,河南師范大學(xué)“優(yōu)秀班主任”

           

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