17. Yuqing Chen; Huaipu Yan; Qian Liao*; Dandan Zhang; Shuangjie Lin;Erjun Hao*; Rukhsana Murtaza;Chenchen Li; Chao Wu; Chunying Duan;Lei shi*;Synthesis of Homoallylic Amines by Radical Allylation of Imines with Butadiene under Photoredox Catalysis，Angew. Chem. Int. Ed. 2022,e202204516.(化學(xué)領(lǐng)域頂尖期刊，SCI一區(qū)，Top，IF16.823)

16.Yonghong Liu, Zhixian Wu, Jingran Shan*, Huaipu Yan, Er-Jun Hao*, Lei Shi*,Titanium catalyzed [2σ+2π] cycloaddition of bicyclo[1.1.0]-butanes with 1,3-dienes for ef?cient synthesis of stilbene bioisosteres, Nature Comm. 2024, 15,4374. (化學(xué)領(lǐng)域頂尖期刊，SCI一區(qū)，Top，IF16.6)

15. Er-Jun Hao, Dan-Dan Fu, Dong-Chao Wang*, Tao Zhang, Gui-Rong Qu，Gong-Xin Li，Yu Lan*, Hai-Ming Guo*，Chemoselective Asymmetric Dearomative [3+2] Cycloaddition Reactions of Purines with Aminocyclopropanes， Org. Chem. Front. 2019,6,863-867. (SCI一區(qū)，Top, IF5.456)

14. Er-Jun Hao, Gong-Xin Li, Zhen-Zhen Lv, Fu-Sheng Li, Yu-Qing Chen, Shuang-Jie Lin, Cai-Zhe Shi, and Lei Shi*，“In-Situ Immobilization” of Multicomponent Chiral Catalyst (MCC) via Non-covalent Interactions for  Heterogeneous Asymmetric Hydrogenation Reactions，Org. Chem. Front. 2020, 7, 345-349. (SCI一區(qū)，Top, IF5.456)

 13.Erjun Hao*, Binghui Lu，Yonghong Liu, Tianxiao Yang, Huaipu Yan, Xiaobo Ding, Yunhe Jin,  Lei Shi*，Difunctionalization of 1,3-Butadiene via Sequential Radical Thiol-ene Reaction and Allylation by Dual Photoredox and Titanium Catalysis，Org. Lett. 2023, 25(27), 5094-5099.(SCI一區(qū)，Top，IF5.2)

12.Huaipu Yan, Dandan Zhang, Yonghong Liu, Xin Wang, Zhixian Wu, Yunhe Jin, Xiaobo Ding, Jingran Shan, Erjun Hao*, Lei Shi*； Photoredox chromium and cobalt dual catalysis for carbonyl allylation with butadiene via allyl radical intermediates,Org. Chem. Front. 2024,11, 684-689. (SCI一區(qū)，IF=5.4，Top)

11.Huaipu Yan,Jing-Ran Shan,Fengzhi Zhang, Yuqing Chen, Xinyi Zhang, Qian Liao, Erjun Hao*, Lei Shi*;  Radical Crotylation of Aldehydes with 1,3-Butadiene by Photoredox Cobalt and Titanium Dual Catalysis，Org. Lett. 2023, 25,7694-7699.(SCI一區(qū)，Top，IF5.2)

10. Shuang-Jie Lin, Yu-Qing Chen, Huai-Pu Yan, Yong-Hong Liu, Yu-Chen Sun, Er-Jun Hao*, Cai-Zhe Shi, Dan-Dan Zhang, Nan Zhu, and Lei Shi*；Activation of Chromium Catalysts by Photoexcited Hantzsch Ester for Decarboxylative Allylation of Aldehydes with Butadiene，Org. Lett. 2021, 23(20), 8077–8081.(SCI一區(qū)，Top，IF6.072)

9. Yonghong Liu,Huaipu Yan, Yuqing Chen, Erjun Hao,* Lei Shi,* Photoinduced copper-catalyzed selective three-component 1,2-amino oxygenation of 1,3-dienes, Chem.Comm. 2023,59,10388-10391. (SCI二區(qū)，IF4.9)

8. Jie Ma, Rong Feng, Hao-Lin Zhou, Er-Jun Hao*, Zhen Shi, and Zhi-Bing Dong*,One Pot Synthesis of N,N-diphenyl-2-benzothiazolamines from 1-(2-Iodophenyl)-3-phenylthioureas and Iodobenzenes, J. Org. Chem. 2022,  87(21), 14342–14351. (SCI二區(qū)，IF4.198)

7.  Xi Wang, Jin-Quan Chen, Xing-Xing Yang, Er-Jun Hao*, Zhi-Bing Dong*,Synthesis of Diaryl Sulfides by Using Tetramethylthiuram Monosulfide (TMTM) as Organosulfur Source: a Practical C(sp2)-S Bond Construction, Eur. J. Org. Chem. 2022,e202200015.(IF3.261)

6.Yue-Xiao Wu; Kang Peng, Zhi-Chao Hu, Yong-Hao Fan, Zhen Shi; Er-Jun Hao*; Zhi-Bing Dong*; Iodine-mediated cross dehydrogenation coupling of heterocyclic thiols with  amines: an easy and practical formation of S-N bond, Eur. J. Org. Chem. , 2021,43: 5889-5894. (IF3.261)

5. Pei-Hua Zhao*, Kuan-Kuan Xiong, Wen-Jun Liang, Er-Jun Hao*，Synthesis, crystal structures and electrocatalytic properties of bridgehead-C- functionalized diiron dithiolate complexes，J. Coord. Chem. 2015, 68,968-979.

4.Gao, Chun; Liu, xin;  Wang, Minghui;  Liu, Shuxian; Zhu, Tingting; Zhang, Yikang; Hao, Erjun*; Yang, Qiliang*;Advances in Electrochemical Asymmetric Synthesis，Chin.J.Org.Chem. 2024,44,673-727.

3.Hao, Erjun*, Ding, Xiaobo, Wang, Kexin, Zhou, Honghao, Yang, Qiliang, Shi, Lei*. Recent Progress on [3+2] Ring-Expansion Reaction of Aziridines with Unsaturated Compounds[J]. Chinese Journal of Organic Chemistry,Chin.J.Org.Chem. 2023,  43：4057-4074.

2. Er-Jun Hao, Qing Zhang, Qi-Ying Zhang*,Gui-Rong Qu, Xi-Ning Yang, Hai-Ming Guo*, Efficient Synthesis of Spirocyclic Nucleosides via Michael-initiated Intermolecular Cyclopropanation Reaction, Chin.J.Org.Chem. 2019, 39,3237-3243.

1. Er-Jun Hao, Xiao-Han Jiang, Dan-Dan Fu, Dong-Chao Wang*, Ming-Sheng Xie, Hai-Ming Guo, Synthesis of  3-Cyanomethyl Oxoindoles via Palladium- catalyzed Domino Heck/Cyanation Reaction in Water,  Chin.J.Org. Chem. 2016, 36, 2746-2751.

近年來(lái)主持的主要科研項(xiàng)目:
1、河南省自然科學(xué)基金重點(diǎn)項(xiàng)目（232300421126），2023.01-2025.12；

2、河南省高等學(xué)校重點(diǎn)科研項(xiàng)目（21A150002），2021.01-2022.12；

3、河南省博士后基金項(xiàng)目（一等資助）(2015071)，2016.01-2019.12；

4、河南省產(chǎn)學(xué)研項(xiàng)目142107000082 ），2015.01-2018.10；

5、河南省高等教育教學(xué)改革研究與實(shí)踐重點(diǎn)項(xiàng)目（2021SJGLX105），2022.01-2023.12。

6、河南省教育廳教師教育課程改革研究重點(diǎn)項(xiàng)目（2014-JSJYZD-012），2014.07-2016.07；

7、河南省教師教育課程改革一般項(xiàng)目（2020-JSJYYB-026 ），2020.06-2021.06；

8、企業(yè)橫向科技合作項(xiàng)目(H20200003)，2020.03-2024.03; 

9、企業(yè)橫向科技合作項(xiàng)目(HJX201819)，2013.11-2018.10；

10、河南師范大學(xué)研究生教育改革與質(zhì)量提升工程項(xiàng)目：研究生課程思政示范課程項(xiàng)目，現(xiàn)代藥劑學(xué)選論（XY2023SZ02），2023.03-2025.03。

近年來(lái)參加的主要科研項(xiàng)目:

1、國(guó)家自然科學(xué)基金聯(lián)合基金重點(diǎn)項(xiàng)目：糖雜環(huán)核苷的設(shè)計(jì)合成、抗腫瘤活性及構(gòu)效關(guān)系研究，U22A20378，2023.01-2026.12，參與，在研；

2、國(guó)家自然科學(xué)基金：電化學(xué)調(diào)控的不對(duì)稱(chēng)反應(yīng)合成手性碳環(huán)核苷，21602045，2017.01-2019.12，參與（第二參與人），已結(jié)題；

3、國(guó)家自然科學(xué)基金：負(fù)載手性催化劑的毛發(fā)狀納米載體的設(shè)計(jì)及其在不對(duì)稱(chēng)反應(yīng)中的應(yīng)用，21204019，2013.01-2015.12，參與（第二參與人），已結(jié)題；

獲得榮譽(yù)與獎(jiǎng)勵(lì)：

1、國(guó)培計(jì)劃、省培計(jì)劃等培訓(xùn)項(xiàng)目可持續(xù)發(fā)展研究與實(shí)踐，河南省教師教育教學(xué)成果獎(jiǎng)二等獎(jiǎng)(豫教〔2021〕58527)；

2、吉西他濱鹽酸鹽生產(chǎn)新工藝研究，河南省人民政府，河南省科技進(jìn)步三等獎(jiǎng)（證書(shū)編號(hào)：2012-J-256-R05/06）；

3、河南師范大學(xué)優(yōu)秀教師；

4、河南師范大學(xué)優(yōu)秀班主任；

5、河南師范大學(xué)優(yōu)秀實(shí)習(xí)指導(dǎo)教師；

6、優(yōu)秀創(chuàng)新創(chuàng)業(yè)指導(dǎo)老師獎(jiǎng)；

7、河南師范大學(xué)文明教師；

8、河南省教育廳優(yōu)秀科技論文二等獎(jiǎng)；

9、化學(xué)化工學(xué)院優(yōu)秀共產(chǎn)黨員；

10、挑戰(zhàn)杯優(yōu)秀指導(dǎo)老師獎(jiǎng)；

11、河南省優(yōu)秀盟員。

代表性授權(quán)國(guó)家發(fā)明專(zhuān)利：

1、郝二軍、郭海明等；[3+2]環(huán)加成不對(duì)稱(chēng)脫芳構(gòu)化合成手性非芳香嘌呤核苷的方法，授權(quán)專(zhuān)利號(hào)：ZL201810894271.4；

2、郝二軍、郭海明等；一種磷酸氟達(dá)拉濱的制備方法，授權(quán)專(zhuān)利號(hào)：ZL201610278259.1；

3、郝二軍、郭海明等；一種合成2′-螺環(huán)基取代的三元碳環(huán)核苷的方法，授權(quán)專(zhuān)利號(hào)：ZL201910374991.2。

4、郭海明、王洋、郝二軍等；非環(huán)核苷先導(dǎo)化合物及其制備方法和在制藥中的應(yīng)用，授權(quán)專(zhuān)利號(hào)：ZL202011489709.4。

English version:

Dr. Er-Jun Hao

School of Chemistry and Chemical Engineering, Henan Normal University

Xinxiang, 453007, China

E-mail: hej@htu.edu.cn

Tel: +86-03733326335 .

Education and Academic career：

Lecturer, Henan Normal University, China(2008)

Ph.D.: Nankai University, China (2010, supervisor: Prof. Xiao-Qing Zhu and  Prof. Jin-Pei Cheng)

M.S.: Henan Normal University, China (2005)

B.S.: Henan Normal University, China (2002)

Major Research Interests：

1. Design and synthesis of chiral nucleoside drugs；

2. Antitumor activity and structure-activity relationship study；

3. Photocatalytic and Electrocatalysis  and Enzyme Catalysis asymmetric synthesis；