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          王鍵吉個人簡介

          時間:2012-11-15瀏覽:27549設(shè)置

           

           

          王鍵吉 博士、教授、博士生導師,河南師范大學校長,國家有突出貢獻的中青年專家、河南省優(yōu)秀專家、中原學者、河南省杰出青年基金、杰出人才基金獲得者、河南省優(yōu)秀科技創(chuàng)新人才獲得者,中國化學會理事、中國化學會化學熱力學專業(yè)委員會副主任、中國化工學會離子液體專業(yè)委員會副主任、國家自然科學基金委化學學科評審組成員、化學重點學科第一學術(shù)帶頭人、綠色化學介質(zhì)與反應教育部重點實驗室主任,  J. Chem. Theromydn., Chin. J. Chem. Phys. 編委.

           

           
                                                                                             因科研需要,本課題組長期招聘博士后研究人員!歡迎報考我課題組研究生。

          教育與研究經(jīng)歷:  
          1975年-1978年,河南師范大學(原新鄉(xiāng)師范學院),化學系,大學
          1978年-1981年,河南師范大學(原新鄉(xiāng)師范學院)化學系,研究生/碩士
          1999年-2001年,日本橫濱國立大學,化學與材料工程系, 研究生/博士
          1981年-1987年,河南師范大學,化學化工學學院,助教、講師
          1987年-1989年,英國London大學,大學學院化學系,訪問學者
          1987年-1991年,河南師范大學,化學化工學學院,副教授
          1992年-1994年,英國Surrey大學,化學系,Research Fellow
          1992年-至今,  河南師范大學,化學化工學學院,教授、博士生導師
          聯(lián)系方式: 
          電話:0373-3325805
          E-mail: Jwang@henannu.edu.cn

          主講課程:
          《物理化學》、《物理化學新進展》、《綠色化學》
          研究領(lǐng)域與興趣:
          1. 功能溶液化學
          2. 基于離子液體的綠色化學
          3. 生物質(zhì)新能源高效利用
          近年來主持的主要科研項目:
          1. 國家863項目(2007AA05Z454): 離子液體分級處理木質(zhì)纖維素原料制備燃料乙醇和氫能新技術(shù)
          2. 國家973前期專項(2011CB211702):功能離子液體低溫溶解/催化木質(zhì)素生成液態(tài)烷烴燃料的研究
          3. 國家863項目(子課題)( 2004AA649030):基于離子液體的酸性有害氣體資源化利用的新技術(shù)—功能化離子液體的制備與物性研究
          4. 國家973項目(子課題)( 2009CB219902) 離子液體的合成、表征及物理化學性質(zhì)研究
          5. 國家自然科學基金重點項目(21133009):離子液體復雜體系化學熱力學與分子間相互作用研究
          6. 國家自然科學基金(21273062): pH 響應離子液體的溶液化學研究
          7. 國家自然科學基金(20873036):離子液體雙水相的微觀結(jié)構(gòu)與萃取分離性能研究
          8. 國家自然科學基金(20573034):室溫離子液體在溶液中的簇集行為研究
          9. 國家自然科學基金(20273019):室溫離子液體中溶質(zhì)-溶劑相互作用規(guī)律研究
          10. 國家自然科學基金(29973009):鋰電池電解質(zhì)溶液中離子溶劑化的熱力學和譜學研究
          11. 國家自然科學基金(29573102):水溶液中電解質(zhì)-糖相互作用規(guī)律的熱力學研究
          12. 國家教委優(yōu)秀年輕教師資助計劃: 氨基酸在蛋白質(zhì)變性劑水溶液中的熱力學和傳輸性質(zhì)研究
          13. 教育部高等學校骨干教師: 鋰電池電解質(zhì)溶液的結(jié)構(gòu)與性能
          14. 教育部高等學校博士點專項科研基金(20060476003):咪唑類離子液體在分子溶劑中的溶劑化學行為研究
          15. 河南省杰出青年基金: 水溶液中電解質(zhì)糖-模型生物分子相互作用的熱力學研究
          16. 河南省杰出人才計劃(08420050015):功能化離子液體的設(shè)計、合成及對生物大分子的選擇性分離
          17. 河南省中原學者計劃(092101510300):離子液體在綠色分離和先進材料制備中的作用機制研究
          18. 日本三菱化學公司研發(fā)基金: 液態(tài)和膠態(tài)介質(zhì)中離子遷移數(shù)測定方法和實驗裝置的研究與開發(fā)
          代表性論文與專利:
          論文:
          在 J.Am.Chem. Soc., Angew. Chem. Int. Ed., Chem. Soc. Rev., Chem. Eur. J., Chem.Comm., Green Chem., Environ.Sci.Technol., J.Phys.Chem., ChemSusChem等SCI期刊發(fā)表論文200余篇,被SCI引用3700余次,代表性論文如下:
          1.張虎成,張立偉,王鍵吉,
          Grafting and Coloring onto Silver Nanoparticles by Photoinduced Surface Modification, J. Am. Chem. Soc., 131 (37), 13206–13207 (2009)

          2.任運來,閆孟杰,王鍵吉,張宗超,姚開勝,Selective Reductive Cleavage of Inert Aryl C-O Bonds by an Iron Catalyst, Angew. Chem. Int. Ed., 52, 12674-12678 (2013).

          3.張鎖江,孫劍,張曉春,辛加余,苗晴晴,王鍵吉,Ionic Liquid-based Green Processes for Energy Production, Chem. Soc. Rev, 2014, DOI: 10.1039/c3cs60409h
          4.裴淵超,王鍵吉,軒小朋,樊靜,范貌宏,F(xiàn)actors affecting ionic liquids based removal of anionic dyes from water, Environ. Sci. Technol., 41, 5090-5095 (2007)

          5.王慧勇,張臘梅,王鍵吉,李志勇,張鎖江,The First Evidence for Unilamellar Vesicle Formation of Ionic Liquids in Aqueous Solutions, Chem. Commun., 49, 5222-5224 (2013)

          6.姚開勝,盧偉偉,李鑫瑩,王鍵吉,元炯亮,Tunable Synthesis of Ag Films at Ionic Liquid-aqueous Interfaces,Chem. Commun., 49, 1398-1400(2013).

          7.王慧勇,王鍵吉,范貌宏,Extraction of Ionic Liquids from Aqueous Solutions by Humic Acid: An Environmentally Benign, Inexpensive and Simple Procedure,Chem. Commun., 48, 392-394 (2012).

          8. 盧偉偉,宋應利,姚開勝,王鍵吉,Thermal-Induced Formation of a Three-Dimensional
          Nanoplasmonic Sensor from Ag Nanocubes with High Stability and Reusability, Chem. Eur. J., 20, 3636-3645 (2014).

          9.熊大珍,王慧勇,李志勇,王鍵吉, Recovery of Ionic Liquids with Aqueous Two-Phase Systems Induced by Carbon Dioxide, ChemSusChem., 5, 2255-2261 (2012).

          10.呂本蓮,許愛榮,王鍵吉,Cation Does Matter: How Cationic Structure Affects the Dissolution of Cellulose in Ionic Liquids, Green Chem., 16, 1326-1335 (2014)

          11.熊大珍,李志勇,王慧勇,王鍵吉,Selective Separation of Aliphatic and Aromatic Amines with CO2 Switchable Ionic Liquids Aqueous Two-phase Systems,  Green Chem., 15, 1941-1948 (2013).
          12.李志勇,劉欣欣,裴淵超,王鍵吉,Design of Environmentally Friendly Ionic Liquids Aqueous Two-phase Systems for the Efficient and High Activity Extraction of Proteins, Green Chem., 14, 2941-2950 (2012).
          13.陳清泰,許愛榮,李志勇,王鍵吉,
          Influence of Anionic Structure on the Dissolution of Chitosan in 1-butyl-3-methylimidazolium-based Ionic Liquids, Green Chem., 13, 3446-3452 (2011).
          14.朱安蓮,李凌君,王鍵吉,卓克壘,
          Direct Nucleophilic Substitution Reaction of Alcohols Mediated by a zinc-based Ionic Liquid, Green Chem., 13, 1244-1250 (2011).

          15.姚開勝,李鑫瑩,盧偉偉,王鍵吉,Tailoring the Properties of Aqueous/Ionic Liquids Interface for Tunable Synthesis and Self-Assembly of ZnS Nanoparticles, J. Mater. Chem. A,  2, 5140-5148 (2014).
          16.王慧勇,馮青琴,王鍵吉,張虎成,Salt Effect on the Aggregation Behavior of 1-Decyl-3-methylimidazolium Bromide in Aqueous Solutions J. Phys. Chem. B, 114,1380-13879 (2010).

          17.趙玉靈,劉曉敏,王鍵吉,張鎖江,Insight into Co-solvent Effect of Cellulose Dissolution in Imidazolium-based Ionic Liquid Systems,  J. Phys. Chem. B, 117, 9042-9049.
          18.趙玉靈,劉曉敏,呂興梅,張鎖江,王鍵吉,
          The Behavior of Ionic Liquids under High Pressure: A Molecular Dynamics Simulation, J. Phys. Chem. B, 116, 10876-10884 (2012).
          19.趙揚,高山嬌,王鍵吉,湯俊明,
          Aggregation of Ionic Liquids [Cnmim]Br (n = 4, 6, 8, 10, 12) in D2O: A NMR Study, J. Phys. Chem. B, 112, 2031-2039 (2008).
          20.王鍵吉,王慧勇,張社利,張虎成,趙揚,
          Conductivities, Volumes, Fluorescence and Aggregation Behavior of Ionic Liquids [C4mim][BF4] and [Cnmim]Br (n=4, 6, 8, 10, 12) in Aqueous Solutions, J. Phys. Chem. B, 111, 6181-6188 (2007).
          21.張虎成, 王鍵吉,鄭洪河,卓克壘,趙揚,
          Interactions of Nanosized Al2O3 and ZnO with Poly(ethylene oxide)-NaSCN Polymer Electrolytes, J. Phys. Chem. B, 109, 2610-2616 (2005).
          22.張虎成,軒小朋,王鍵吉,汪漢卿,
          Vibrational Spectroscopic Studies on Interactions in PEO- NaSCN-urea Composites, J. Phys. Chem. B, 108, 1563-1569 (2004).
          23.鄭勇,軒小朋,王鍵吉,范貌宏,
          The Enhanced Dissolution of β-Cyclodextrin in Some Hydrophilic Ionic Liquids J. Phys. Chem. A, 114, 3926-3931 (2010).
          24.軒小朋,張虎成,王鍵吉,汪漢卿,
          Vibrational Spectroscopic and Density Functional Studies on Ion Solvation and Association of Lithium Tetrafluorobrate in Acetonitrile, J. Phys. Chem. A, 108, 7513-7521 (2004).
          25.許愛榮,王鍵吉,王慧勇,
          Effects of Anionic Structure and Lithium Salts Addition on the Dissolution of Cellulose in 1-butyl-3-methylimidazolium-based Ionic Liquid Solvent Systems, Green Chem., 12, 268-275 (2010)
          26.王鍵吉, 裴淵超,趙揚,胡治國,
          Recovery of Amino Acids by Imidazolium Based Ionic Liquids from Aqueous Media, Green Chem., 7, 196-202 (2005)
          27.王鍵吉,田勇,趙揚, 卓克壘,
          A Volumetric and Viscosity Study for the Mixtures of 1-n-butyl- 3- methylimidazolium Tetrafluoroborate Ionic Liquid with Acetonitrile, Dichloromethane, 2-Butanone and N,N-dimethylformamide, Green Chem., 5, 618-622 (2003)
          28.張新迎,范學森,牛紅英,王鍵吉,An Ionic Liquid as a Recyclable Medium for the Green Preparation of α, α’-bis (substituted benzylidene)cycloalkanones Catalyzed by FeCl3·6H2O, Green Chem., 5, 267-269 (2003).

          29.吳長增,王鍵吉,李志勇,荊俊,王慧勇,Relative Hydrophobicity between the Phases and Partition of Cytochrome-c in Glycine Ionic Liquids Aqueous Two-phase Systems,  J. Chromat. A., 1305, 1-6 (2013).

          30.吳長增,王鍵吉,王慧勇,裴淵超,李志勇, Effect of Anionic Structure on the Phase Formation and Hydrophobicity of Amino Acid Ionic Liquids Aqueous Two-phase Systems, J. Chromat. A., 1218, 8587-8593 (2011)
          31.李志勇,裴淵超,王慧勇,樊靜,王鍵吉,
          Ionic liquids based aqueous two-phase systems and their applications in green separation process, Trends Anal. Chem., 29, 1336-1346 (2010).
          32.王慧勇,王鍵吉,張社利,裴淵超,卓克壘,
          Ionic Association of the Ionic Liquids [C4mim][BF4], [C4mim][PF6], and [Cnmim]Br in Molecular Solvents. ChemPhysChem., 10, 2516–25232 (2009)
          33.王慧勇,王鍵吉,張仕彪,
          Binding Gibbs Energy of Ionic Liquids to Calf thymus DNA: a Fluorescence Spectroscopy Study, Phys. Chem. Chem. Phys., 13, 3906-3910 (2011)

          34.趙玉靈,劉曉敏,王鍵吉,張鎖江,Effects of Anionic Structure on the Dissolution of Cellulose in Ionic Liquids Revealed by Molecular Simulation, Carbonhydrate Polymers, 94, 723-730 (2013).

          35.許愛榮,張亞娟,趙揚,王鍵吉,Cellulose Dissolution at Ambient Temperature: Role of Preferential Solvation of Cations of Ionic Liquids by a Cosolvent, Carbonhydrate Polymers, 92, 540-544 (2013). 

          36.趙揚,崔桂榮,王鍵吉,范貌宏, Effects of Ionic Liquids on the Characteristics of Synthesized Nano Fe(0) Particles, Inorg. Chem., 48, 10435–10441 (2009)
          37.趙揚,陳震華,王慧勇,王鍵吉,
          Crystallization Control of CaCO3 by Ionic Liquids in Aqueous Solution, Crystal Growth & Design, 9, 4984-4986 (2009)

          38.李鑫瑩,姚開勝,盧偉偉,王鍵吉,F(xiàn)acile Interfacial Synthesis of Gold Micro/nanostructures and Their Applications for Efficient Surface Enhanced Raman Scattering , CrystEngComm, 15, 1289-1292 (2013).

          39.周海梅,呂萍,申圓圓,王鍵吉,樊靜,Identification of Degradation Products of Ionic Liquids in an Ultrasound Assisted Zero-valent iron Activated Carbon Micro-electrolysis System and Their Degradation Mechanism, Water Res., 47, 3514-3522 (2013) .

          40.周海梅,申圓圓,呂萍,王鍵吉,樊靜,Degradation of 1-butyl-3-methylimidazolium Chloride Ionic Liquid by Ultrasound and Zero-valent iron/activated Carbon, Separ. Purif. Technol.,  104, 208-213 (2013).

          41.裴淵超,王鍵吉,武坤,軒小朋,盧新杰,Ionic Liquid-based Aqueous Two-phase Extraction of Selected Proteins, Separ. Purif. Technol.,  64, 288-295 (2009)
          42. 樊靜,范云場,裴淵超,武坤,王鍵吉, Solvent Extraction of Selected Endocrine-disrupting Phenols using Ionic Liquids, Sep. Purif. Technol., 61, 324-331 (2008)
          43.張虎成, 王鍵吉, 軒小朋,卓克壘,F(xiàn)T-IR Studies on Interactions of AlCl3 with PEO-NaSCN Polymer Electrolytes, Electrochim. Acta, 51, 3244-3248 (2006)
          44.軒小朋, 王鍵吉,汪漢卿, Theoretical Insights into PF6- and its Alkali Metal Ion Pairs: Geometries and Vibrational Frequencies, Electrochim. Acta, 50, 4196-4201 (2005)
          45.軒小朋, 王鍵吉,趙揚,朱建軍,Experimental and Computational Studies on the Solvation of Lithium Tetrafluorobrate in Dimethylsulfoxide, J. Raman Spectrosc., 38, 865-872 (2007)
          46.軒小朋,張虎成,王鍵吉,汪漢卿, Raman Spectroscopic and DFT Studies on Solutions of NaBF4 in N,N-dimethylformamide, J. Raman Spectrosc., 34, 465-470 (2003)
          47.馮青琴,王慧勇,張仕彪,王鍵吉,Aggregation Behavior of 1-Dodecyl-3-methylimidazolium Bromide Ionic Liquid in non-aqueous Solvents, Colloids and Surfaces A: Physicochem. Eng. Aspects, 367, 7-11 (2010)
          48.軒小朋, 王鍵吉,趙揚,張虎成, FT-Raman Spectroscopic Evidences for the Preferential Solvation of Sodium Tetrafluorobrate in Acetonitrile-based Mixed Solvents, Spectrochim. Acta A, 62, 500-505 (2005)
          49.王鍵吉,吳艷平,軒小朋,汪漢卿, Ion-molecule Interactions in Solutions of Lithium Perchlorate in Propylene Carbonate + Diethyl Carbonate Mixtures: an IR and Molecular Orbital Study, Spectrochim. Acta, A, 58, 2097-2104 (2002)
          50.朱安蓮,王鍵吉,韓麗君,范貌宏, Measurements and Correlation of Viscosities and Conductivities for the Mixtures of Imidazolium Ionic Liquids with Molecular Solutes, Chem. Eng. J., 147, 27-35 (2009)
          51.王鍵吉,張仕彪,王慧勇,裴淵超, Apparent Molar Volumes and Electrical Conductance of Ionic Liquids [Cnmim]Br (n=8, 10, 12) in Ethylene Glycol, N,N-Dimethylformamide, and Dimethylsulfoxide at 298.15 K, J. Chem. Eng. Data, 54, 3252-3258 (2009)
          52.吳長增,王鍵吉,裴淵超,王慧勇,李志勇,Salting-Out Effect of Ionic Liquids on Poly(propylene glycol) (PPG): Formation of PPG + Ionic Liquid Aqueous Two-Phase Systems, J. Chem. Eng. Data, 55, 5004-5008 (2010)
          53.裴淵超,王鍵吉,劉麗,武坤,趙揚,Liquid-liquid Equilibria of Aqueous Biphasic Systems Containing Selected Imidazolium Ionic Liquids and Salts, J. Chem. Eng. Data, 52, 2026-2031 (2007)
          54.李志勇,裴淵超,劉麗,王鍵吉, (Liquid+liquid) Equilibria for (Acetate-based Ionic Liquids + Inorganic Salts) Aqueous Two-phase Systems, J. Chem. Thermodyn. 2010, 42, 932-937 (2010)
          55.王鍵吉,朱安蓮,趙揚,卓克壘,Excess Molar Volumes and Excess Logarithm Viscosityes for Binary Mixtures of the Ionic Liquid 1-Butyl-3-methylimidazolium Hexafluophosphate with Some Organic Compounds, J. Solution Chem., 34, 585-596 (2005)
          專利:
          1.樊靜,吳春來,王鍵吉,彭傳云,魏婭方,梁峰,茜素紫鍵合硅膠固相萃劑的合成方法,中國發(fā)明專利,專利號: ZL 200710054167.6

          2.劉振, 王鍵吉, 尹衛(wèi)平, 楊敏,天然纖維素原料經(jīng)離子液體分級處理一步發(fā)酵制備乙醇的方法,中國發(fā)明專利,專利號:ZL 200810095798.7

          3.劉振,王鍵吉,尹衛(wèi)平,任運來,任云利,利用離子液體生產(chǎn)乙醇的方法,中國發(fā)明專利,專利號:ZL201010030128.4

          4.劉振,王鍵吉,郝靜靜,陳競一,常慶輝,一種磁場輔助氣提發(fā)酵生產(chǎn)乙醇的方法,中國發(fā)明專利,專利號: ZL 201110171615.7

          5.劉振,王鍵吉,常慶輝,陳競一,張輝,孫鮮明,馬建華,一種發(fā)酵制氫中氫氣的分離裝置,中國實用新型專利,專利號:,ZL 201220353776.8
          6.王鍵吉,許愛榮,樊靜,軒小朋,一種纖維素的溶劑,中國發(fā)明專利,申請?zhí)枺?00910065084.6

          著作:
          張鎖江, 王鍵吉, 呂興梅, 周清,Structures and Interactions of Ionic Liquids, Springer, 2014

          成果獎勵:
          1. 離子液體的構(gòu)效關(guān)系及其化學工程基礎(chǔ)研究, 2010年國家自然科學二等獎
          2. 糖和氨基酸與電解質(zhì)弱相互作用的熱力學研究,2004年河南省科技進步一等獎
          3. 鋰離子電池電解質(zhì)的微觀結(jié)構(gòu)研究,2009年河南省科技進步一等獎

           

           

           

           

           

           
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