張凱歌 女,重點(diǎn)學(xué)科秘書(shū),博士,副教授,碩士生導(dǎo)師,1986年3月出生,河南禹州人。主要從事新型分離介質(zhì)在復(fù)雜體系(環(huán)境、食品和生物)中的應(yīng)用研究。主持國(guó)家自然科學(xué)基金、中國(guó)博士后科學(xué)基金、河南省重點(diǎn)科技攻關(guān)、“i科普”科技志愿服務(wù)和河南省高等學(xué)校重點(diǎn)科研等項(xiàng)目8項(xiàng);在Nanoscale, Trends in Analytical Chemistry, Food chemistry, Journal of Chromatography A, Talanta, Microchimica Acta等國(guó)內(nèi)外學(xué)術(shù)期刊上發(fā)表論文20余篇;授權(quán)發(fā)明專(zhuān)利4件。1次參加國(guó)際會(huì)議并作口頭報(bào)告。
受教育經(jīng)歷(:
2011/09-2015/06,中山大學(xué),化學(xué)與化學(xué)工程學(xué)院,分析化學(xué)專(zhuān)業(yè),博士
2008/09-2011/06,河南工業(yè)大學(xué),化學(xué)與化學(xué)工程學(xué)院,分析化學(xué)專(zhuān)業(yè),碩士
2004/09-2008/06,信陽(yáng)師范學(xué)院,化學(xué)與化學(xué)工程學(xué)院,理學(xué)學(xué)士
環(huán)境分析、功能分離介質(zhì)研制
主持的科研項(xiàng)目:
1. 國(guó)家自然科學(xué)基金青年科學(xué)基金項(xiàng)目,磁性分子印跡表面增強(qiáng)拉曼活性基底的研制及其在痕量環(huán)境污染物快檢中的應(yīng)用 (21605040),2017/01-2019/12,20萬(wàn)
2. 河南省重點(diǎn)科技攻關(guān)項(xiàng)目, 聚合低共熔溶劑功能化磁性納米材料對(duì)黃河流域水體抗生素類(lèi)PPCPs的分離富集及去除 (212102310533),2021/01-2022/12
3. 中國(guó)博士后科學(xué)基金項(xiàng)目,功能化磁性拉曼活性基底的研制及其在環(huán)境分析中的應(yīng)用 (2016M592295),2016/01-2017/12,5萬(wàn)
4. 河南省高等學(xué)校重點(diǎn)科研項(xiàng)目,聚合低共熔溶劑功能化磁性納米材料在環(huán)境水體紫外吸收劑分離富集中的應(yīng)用 (22A610005), 2022/01-2023/12,5萬(wàn)元
5. “i科普”科技志愿服務(wù)項(xiàng)目,科普進(jìn)校園,智慧新生活,2020/01-2020/12,3萬(wàn)
6. 河南省高等學(xué)校重點(diǎn)科研項(xiàng)目,功能化磁性SERS活性基底的研制及其在環(huán)境污染物檢測(cè)中的應(yīng)用 (16A610003),2016/01-2017/12,5萬(wàn)
7. 河南師范大學(xué)博士科研啟動(dòng)項(xiàng)目,功能化磁性SERS活性基底的研制及其在環(huán)境污染物檢測(cè)中的應(yīng)用 (51012190110),2016/01-2018/12,8萬(wàn)
8. 河南師范大學(xué)博士后科研啟動(dòng)項(xiàng)目,磁性復(fù)合納米活性基底研制及表面增強(qiáng)拉曼光譜應(yīng)用 (51012190010),2016/01-2017/12,3萬(wàn)
參加的科研項(xiàng)目:
1. 國(guó)家自然科學(xué)基金面上項(xiàng)目,分子印跡-金屬有機(jī)骨架復(fù)合材料的可控構(gòu)建及其對(duì)環(huán)境激素和抗生素的分離富集 (21876045),2019/01-2022/12,65萬(wàn)元
2. 國(guó)家自然科學(xué)基青年科學(xué)基金項(xiàng)目,基于零背景和多元信號(hào)放大的新型核酸生物傳感器的構(gòu)建及其對(duì)癌癥標(biāo)記物的高靈敏檢測(cè) (21705034),2018/01- 2020/12,25萬(wàn)元
3. 國(guó)家重大科學(xué)儀器設(shè)備開(kāi)發(fā)項(xiàng)目,等離激元增強(qiáng)拉曼光譜儀器研發(fā)與應(yīng)用 (2011YQ03012409)-任務(wù)9,2011/10-2015/09,615萬(wàn)
4. 國(guó)家自然科學(xué)基金面上項(xiàng)目,水體中激素類(lèi)PPCPs原位富集、表面增強(qiáng)拉曼光譜快速檢測(cè)新方法及其應(yīng)用研究 (21277176),2013/01-2016/12,80萬(wàn)
5. 國(guó)家自然科學(xué)基金面上項(xiàng)目,循環(huán)動(dòng)態(tài)在線(xiàn)分析系統(tǒng)研制與應(yīng)用研究 (21475153),2015/01-2018/12,100 萬(wàn)
6. 國(guó)家基金委儀器專(zhuān)項(xiàng),復(fù)雜體系多功能在線(xiàn)樣品前處理聯(lián)用系統(tǒng)的研制 (21127008),2012/01-2015/12,280萬(wàn)
代表性論文:
1. Zhang Kaige*, Guo Rong, Wang Yunhe, Nie Qiujun, Zhu Guifen*. One-step derivatization and temperature-controlled vortex-assisted liquid-liquid microextraction based on the solidification of floating deep eutectic solvents coupled to UV-Vis spectrophotometry for the rapid determination of total iron in water and food samples, Food Chemistry, 2022, 384: 132414.
2. Zhang Kaige*, Wang Yunhe, Li Shuangying, Zhu Guifen*. Air-assisted liquid-liquid microextraction based on the solidification of floating deep eutectic solvents for the simultaneous determination of bisphenols and polycyclic aromatic hydrocarbons in tea infusions via HPLC, Food Chemistry, 2021, 348: 129106.
3. Zhang Kaige*, Li Shuangying, Wang Yunhe, Fan Jing, Zhu Guifen*. Air-assisted liquid-liquid microextraction based on solidification of floating deep eutectic solvent for the analysis of ultraviolet filters in water samples by high performance liquid chromatography with the aid of response surface methodology. Journal of Chromatography A, 2020, 1618: 460876.
4. Zhang Kaige*, Liu Chuang, Li Shuangying, Wang Yunhe, Zhu Guifen, Fan Jing*. Vortex-assisted liquid-liquid microextraction based on a hydrophobic deep eutectic solvent for the highly efficient determination of Sudan I in food samples. Analytical Letters, 2020, 53: 1204-1217.
5. Cheng Guohao, Yu Wenna, Yang Can, Li Shiying, Wang Xiaoyue, Wang Peiyun, Zhang Kaige*, Li Xiang, Zhu Guifen*. Highly selective removal of 2,4-dinitrophenol by a surface imprinted sol-gel polymer. Journal of Applied Polymer Science, 2020, 137: 49236.
6. Zhang Kaige, Liu Chuang, Li Shuangying, Fan Jing*. A hydrophobic deep eutectic solvent based vortex-assisted liquid-liquid microextraction for the determination of formaldehyde from biological and indoor air samples by high performance liquid chromatography. Journal of Chromatography A, 2019, 1589: 39-46.
7. Zhu Guifen*, Li Wanwan, Wang Peiyun, Cheng Guohao, Chen Letian, Zhang Kaige*, Li Xiang. One-step polymerization of hydrophilic ionic liquid imprinted polymer in water for selective separation and detection of levofloxacin from environmental matrices. Journal of Separation Science, 2019, 43: 639-647.
8. Zhang Kaige*, Li Shuangying, Liu Chuang, Wang Qi, Wang Yunhe, Fan Jing*. A hydrophobic deep eutectic solvent-based vortex-assisted dispersive liquid-liquid microextraction combined with HPLC for the determination of nitrite in water and biological samples. Journal of Separation Science, 2018, 42: 574-581.
9. 張凱歌*, 王云鶴, 李雙瑩, 樊靜*. 二苯碳酰二肼光度法測(cè)定鉻(VI)不足及改進(jìn). 化學(xué)教育, 2019, 40: 49-52.
10. Zhang kaige, Hu yuling*, Li gongke*. In situ loading of very-dispersed silver nanoparticles on nanocrystalline magnesium oxide for real-time monitoring of catalytical reactions by surface enhancement Raman spectroscopy. Nanoscale, 2015, 7: 16952-16959.
11. Zhang Kaige, Yao Su, Li Gongke*, Yuling Hu*.One-step sonoelectrochemical fabrication of gold nanoparticles/carbon nanosheet hybrids for efficient surface-enhanced Raman scattering. Nanoscale, 2015, 7: 2659-2666.
12. Zhang Kaige, Liang Lizhen, Huang Meiying, Hu Yuling*, Li Gongke*. Determination of iodate in iodized salt and water samples by shell-isolated nanoparticle-enhanced Raman spectroscopy. Microchimica Acta, 2014, 181: 1301-1308.
13. Zhang Kaige, Hu Yuling*, Li Gongke*. Diazotization-coupling reaction-based selective determination of nitirte in complex samples using shell-isolated nanoparticle-enhanced Raman spectroscopy. Talanta, 2013, 116: 712-718.
14. He Lijun*, Zhang Kaige, Luo Xianli, Wang Caijuan, Zhang Shusheng. Effective indirect enrichment and determination of nitrite ion in water and biological samples using ionic liquid-dispersive liquid-liquid microextraction combined with high-performance liquid chromatography. Journal of Chromatography A, 2011, 1218: 3595-3600.
15. Hu Yuling*, Pan Jialiang, Zhang Kaige, Lian Haixian, Li Gongke*. Novel applications of molecularly-imprinted polymers in sample preparation. Trends in Analytical Chemistry, 2013, 43: 37-52.
16. 張凱歌, 胡玉玲*, 胡玉斐, 李攻科*. 分子印跡微萃取技術(shù)的研究進(jìn)展. 色譜, 2012, 12: 1220-1228. (核心期刊)
17. 張凱歌, 何麗君*. 基于 [HMIM][Tf2N] 的分散液液微萃取氨基甲酸酯. 西北大學(xué)學(xué)報(bào) (自然科學(xué)版), 2010, 40: 101-102.
授權(quán)專(zhuān)利成果:
1. 張凱歌, 樊靜, 劉闖, 李雙瑩, 杜亭如, 趙揚(yáng)揚(yáng). 疏水性低共熔溶劑渦旋輔助分散液液微萃取-高效液相色譜法檢測(cè)甲醛的方法, 2020-11-6, 中國(guó), ZL201810671110 .9
2. 張凱歌, 樊靜; 劉闖; 李雙瑩; 趙揚(yáng)揚(yáng); 杜亭如 ; 疏水性低共熔溶劑渦旋輔助分散液液微萃取-高效液相色譜法檢測(cè)蘇丹紅I的方法, 2020-10-2, 中國(guó), ZL201810672553 .X
3. 樊靜, 張凱歌, 李雙瑩, 劉闖, 李想, 張霞. 疏水性低共熔溶劑渦旋輔助分散液液微萃取-高效液相色譜法檢測(cè)亞硝酸根的方法, 2020-9-22, 中國(guó), ZL201810671068.0
4. 李攻科, 張凱歌, 胡玉玲. 表面增強(qiáng)拉曼光譜快速檢測(cè)亞硝酸根方法及其應(yīng)用. 2016-2-1, 中國(guó), ZL102998298A